电解质
法拉第效率
材料科学
化学工程
电化学
阴极
聚合
电池(电)
相间
硫黄
锂硫电池
分离器(采油)
电极
化学
复合材料
聚合物
物理
工程类
热力学
物理化学
功率(物理)
冶金
生物
量子力学
遗传学
作者
Jiahang Chen,Huichao Lü,Qian Zhang,Yu Zhang,Jun Yang,Yanna NuLi,Yudai Huang,Jiulin Wang
标识
DOI:10.1016/j.ensm.2022.05.044
摘要
Lithium-sulfur battery has received wide interest owing to its high theoretical energy density and abundant sulfur resources. Sulfurized pyrolyzed poly(acrylonitrile) ([email protected]) cathode can eliminate the shuttle effect owing to solid-solid conversion mechanism while suffers poor electrolyte/electrodes interphase and sluggish kinetics in carbonate electrolyte. Herein, an in-situ electrochemical polymerization is firstly proposed to form a nonflammable polyether electrolyte for [email protected] battery, which enables superior lithium compatibility (over 3000 h) and modifies the cathode interphase with promoted kinetics. The polyether-rich interphase ensures high capacity (1645.3 mAh g−1 based on sulfur), fast-charging ability (10 C) and remarkable cycling stability (99.5% retention over 400 cycles) with ultrahigh average Coulombic efficiency (CE) over 99.9995%, indicating nearly no irreversible reaction on cathode. The pouch cell delivers high sulfur utilization of 91.2% and stable performance with 84.6% capacity retention over 60 cycles.
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