Solid Base Assisted Dual‐Promoted Heterogeneous Conversion of PVC to Metal‐Free Porous Carbon Catalyst

Polyvinyl chloride (PVC) is widely used in daily life, but its waste has become a serious environmental problem. A solid base assisted low-temperature solvothermal dehalogenation was developed in this work to sustainably and efficiently transform PVC into high-value dimethylamine hydrochloride (DMACl) chemical and N,O co-doped carbon monolith with hierarchically porous structure. The synergistic promotion of solid-base catalyst and solvent decomposition with the removal of HCl can shift forward the chemical equilibrium to promote the dechlorination of PVC and increase the carbon yield. Meanwhile, the solid-base catalyst can also act as a pore-forming additive to fabricate the carbon monolith with hierarchical pores. Induced by the high specific surface area, hierarchical pores and N,O co-doped structure, the generated carbon monolith exhibits superior electrocatalytic performance towards H2 evolution. These discoveries shed light on the design of synergistically coupled solvent and solid catalyst to promote the heterogeneous conversion of waste chlorinated plastics into high-value chemicals for a sustainable future.