聚丙烯腈
静电纺丝
材料科学
纳米纤维
退火(玻璃)
化学工程
循环伏安法
碳纳米纤维
纳米技术
电化学
电极
碳纳米管
复合材料
化学
聚合物
物理化学
工程类
作者
Jiandong Liu,Jiaojiao Liang,Caiyun Wang,Jianmin Ma
标识
DOI:10.1016/j.jechem.2018.09.006
摘要
One-dimensional nano-structured materials have attracted attention due to its unique properties afforded such as the across-linked structures and large aspect ratios. In this work, one-dimensional [email protected] carbon nanofibers ([email protected] NFs) are successfully by combining the techniques of electrospinning and annealing. Selenium powder are directly dispersed in the polyacrylonitrile /N,N-Dimethylformamide (DMF) solution containing cobalt salt to form the product. The performance of these materials was investigated in Li-ion batteries after the annealing at different temperatures. The [email protected] nanofibers annealed at 550 °C ([email protected]) and displayed excellent storage properties, affording a high capacity of 796 mAh·g−1 at a current density of 1 A·g−1 for 100 cycles. Moreover, it is confirmed that the pseudocapacitive contribution of [email protected] is up to 72.8% at the scan rate of 1 mV/s through the cyclic voltammetry analysis.
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