单斜晶系
发光
拉曼光谱
硫酸盐
晶体结构
结构精修
离子
红外光谱学
傅里叶变换红外光谱
结晶学
化学
光谱学
红外线的
分析化学(期刊)
材料科学
光学
物理
量子力学
有机化学
光电子学
色谱法
作者
Yuriy G. Denisenko,Aleksandr S. Aleksandrovsky,Victor V. Atuchin,А. С. Крылов,Maxim S. Мolokeev,Aleksandr S. Oreshonkov,N. P. Shestakov,О. В. Андреев
标识
DOI:10.1016/j.jiec.2018.07.034
摘要
Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm−1 and ν2 modes below 500 cm−1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.
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