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Performance of thermally conductive NR composites reinforced with stearic acid‐modified microcrystalline cellulose: A combined experimental and molecular dynamic simulation study

材料科学 复合材料 微晶纤维素 天然橡胶 氮化硼 硬脂酸 极限抗拉强度 纤维素 热导率 复合数 化学工程 工程类
作者
Zhen Wang,Zhenlu Li,Dongming Chen,Zhengying Qin,Linquan Wang,Xianhui Zhang,Ziwei Li,Shaorong Lu
出处
期刊:Polymer Composites [Wiley]
卷期号:45 (3): 2841-2857 被引量:8
标识
DOI:10.1002/pc.27974
摘要

Abstract With the increasing environmental requirements for improving products and materials using renewable and sustainable resources, cellulose has been seen as one of the most attractive and promising alternatives to traditional inorganic fillers. We developed a new modification method to improve the interface compatibility between natural rubber and sisal cellulose, to improve the mechanical and thermal conductivity properties of rubber composite. Microcrystalline cellulose (MCC) was extracted from sisal cellulose and then the hydrophobic cellulose (SA‐MCC) was prepared by grafting stearic acid on the surface of MCC. MCC and SA‐MCC were added to the thermal conductivity composite material composed of natural rubber and boron nitride. The results showed that the thermal conductivity and tensile properties of the natural rubber composites increased by 17.3% and 20%, respectively, under the addition of 1.8 wt% SA‐MCC. Furthermore, the interfacial interaction between the components in the composite was studied by molecular dynamics simulation. The solubility parameters, free volume fraction, and molecular binding energy were calculated to verify the effectiveness of the modification. This work is expected to provide a theoretical basis for the design and preparation of high‐performance natural rubber composite materials. Highlights Cellulose microcrystals were successfully extracted from sisal fiber and modified. Through the combination of boron nitride and the modified cellulose microcrystals, the thermal conductivity and tensile properties of thermal rubber were successfully improved synchronously. A reasonable molecular simulation model was established to analysis the strengthening mechanism from the microscopic point of view. The molecular simulation conclusions on interface enhancement are in good agreement with the experimental properties.
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