Upcycling End of Life Solar Panels to Lithium‐Ion Batteries Via a Low Temperature Approach

The massive adoption of renewable energy especially photovoltaic (PVs) panels is expected to create a huge waste stream once they reach end-of-life (EoL). Despite having the highest embodied energy, present photovoltaic recycling neglects the high purity silicon found in the PV cell. Herein, a scalable and low energy process is developed to recover pristine silicon from EoL solar panel through a method which avoids energy-intensive high temperature processes. The extracted silicon was upcycled to form lithium-ion battery anodes with performances comparable to as-purchased silicon. The anodes retained 87.5 % capacity after 200 cycles while maintaining high coulombic efficiency (>99 %) at 0.5 A g-1 charging rate. This simple and scalable process to upcycle EoL-solar panels into high value silicon-based anodes can narrow the gap towards a net-zero waste economy.