Unlocking Topological Effects in Covalent Organic Frameworks for High‐Performance Photosynthesis of Hydrogen Peroxide

Covalent organic frameworks (COFs) offer a compelling platform for the efficient photosynthesis of hydrogen peroxide (H₂O₂). Constructed with diverse topologies from various molecular building units, COFs can exhibit unique photocatalytic properties. In this study, three π-conjugated 2D sp² carbon-linked COFs with distinctly different topologies (hcb, sql, and hxl) are designed to investigate the topological effect on the overall photosynthesis of H₂O₂ from water and oxygen. Despite their similar chemical and band structures, the QP-HPTP-COF with hxl topology outperformed other COFs in the photosynthesis of H₂O₂, demonstrating a remarkable solar-to-chemical conversion efficiency of 1.41%. Comprehensive characterizations confirmed that the hxl topology can substantially improve charge separation and transfer, thereby significantly enhancing photocatalytic performance. This study not only unravels the topology-directed charge carrier dynamics in COFs but also establishes a molecular engineering framework for developing high-performance photocatalysts for sustainable H₂O₂ production.