电解质
法拉第效率
电池(电)
石墨
电化学
自放电
离子液体
插层(化学)
碳纤维
电极
化学
分解
化学工程
材料科学
无机化学
有机化学
复合材料
复合数
催化作用
物理化学
功率(物理)
工程类
物理
量子力学
作者
Alisha Yadav,Hironobu Kobayashi,Takafumi Nikaido,Takayuki Yamamoto,Toshiyuki Nohira
标识
DOI:10.1016/j.jpowsour.2023.233628
摘要
Dual-carbon batteries (DCBs) have attracted considerable attention as they are environmentally friendly, economical, and exhibit a high cost-to-performance ratio. However, severe electrolyte decomposition and Al current collector corrosion lead to moderate reversible capacity and low average coulombic efficiency in DCBs, limiting their practical application. This paper reports a potassium-based DCB using a pure ionic liquid (IL) electrolyte with asymmetric FTA− anions (FTA = (fluorosulfonyl)(trifluoromethylsulfonyl)amide) and graphite electrodes, with a high charge–discharge capacity and long cycle-life. ILs are intrinsically highly concentrated electrolytes composed of cations and anions that enable the construction of high energy density DCBs. Here, symmetric dual-carbon full cells with the FTA-based IL electrolyte and graphite positive and negative electrodes delivered a high discharge capacity of 81 mAh g−1 with an average discharge voltage of ∼4.35 V up to 300 cycles. Further, ex-situ X-ray diffraction measurements conducted at 298 K indicated the formation of stage 1 FTA-graphite intercalation compounds at the full-charged state. This study facilitates the construction of cost-effective DCBs with a high operating voltage, fast charge–discharge, and long cycling, without the use of toxic metals.
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