离域电子
未成对电子
铂金
桥接(联网)
半导体
分子
材料科学
电导率
顺磁性
金属
电子
无机化学
化学
纳米技术
化学物理
凝聚态物理
物理化学
光电子学
计算机科学
物理
冶金
催化作用
量子力学
有机化学
计算机网络
作者
Kazuhiro Uemura,Momoka Oshika,Haruka Hasegawa,Atsushi Takamori,Masahiro Sato
标识
DOI:10.1002/anie.202413887
摘要
Spherical polyoxometalates, which are insulators, were successfully transformed into semiconductors by linking them with one-dimensional multinuclear platinum complexes. The assembles comprising two kinds of molecules are paramagnetic due to mixed-valent metal oxidation states, where unpaired electrons are delocalized over these backbones. Various derivatives with bandgap modulations are expected, represented by the flow of electricity in electronic circuits containing them, as reported by Kazuhiro Uemura et al. in their Research Article (e202407743).
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