The Conjugated/Non‐Conjugated Linked Dimer Acceptors Enable Efficient and Stable Flexible Organic Solar Cells

Abstract The fabrication of the flexible devices with excellent photovoltaic performance and stability is critical for the commercialization of organic solar cells (OSCs). Herein, the conjugated dimer acceptor DY‐TVCl and the non‐conjugated dimer acceptor DY‐3T based on the monomer MY‐BO are synthesized to regulate the molecular glass transition temperatures ( T g ) for improving the morphology stability of active layer films. And the crack onset strain values for the blend films based on dimer acceptors are superior than that of small molecule, which are beneficial for the preparation of flexible devices. Accordingly, the binary device based on PM6:DY‐TVCl achieves a maximum power conversion efficiency (PCE) of 18.01%. Meanwhile, the extrapolated T 80 (time to reach 80% of initial PCE) lifetimes of the PM6:DY‐TVCl‐based device and PM6:DY‐3T‐based device are 3091 and 2227 h under 1‐sun illumination, respectively, which are better than that of the PM6:MY‐BO‐based device (809 h). Furthermore, the flexible devices based on DY‐TVCl and DY‐3T exhibit the efficiencies of 15.23% and 14.34%, respectively. This work affords a valid approach to improve the stability and mechanical robustness of OSCs, as well as ensuring the reproducibility of organic semiconductors during mass production.