(NHC)CuI (NHC = N-Heterocyclic Carbene) Complexes as Efficient Catalysts for the Reduction of Carbonyl Compounds
卡宾
化学
硅氢加成
催化作用
盐（化学）
药物化学
有机化学
高分子化学
作者
Harneet Kaur,Fabiano Kauer Zinn,Edwin D. Stevens,Steven P. Nolan
出处
期刊：Organometallics [American Chemical Society] 日期：2004-02-04卷期号：23 (5): 1157-1160被引量：290
标识
DOI：10.1021/om034285a
摘要
The hydrosilylation of various ketones is mediated by an imidazolium salt/Cu(I) salt system or by a well-defined (NHC)CuCl (NHC = N-heterocyclic carbene) catalyst precursor system. Reactions are conducted at room temperature. The synthesis and characterization of well-defined (NHC)CuCl complexes are described.
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