A Chemically Stable Hofmann‐Type Metal−Organic Framework with Sandwich‐Like Binding Sites for Benchmark Acetylene Capture

Abstract The realization of porous materials for highly selective separation of acetylene (C 2 H 2 ) from various other gases (e.g., carbon dioxide and ethylene) by adsorption is of prime importance but challenging in the petrochemical industry. Herein, a chemically stable Hofmann‐type metal−organic framework (MOF), Co(pyz)[Ni(CN) 4 ] (termed as ZJU‐74a), that features sandwich‐like binding sites for benchmark C 2 H 2 capture and separation is reported. Gas sorption isotherms reveal that ZJU‐74a exhibits by far the record C 2 H 2 capture capacity (49 cm 3 g −1 at 0.01 bar and 296 K) and thus ultrahigh selectivity for C 2 H 2 /CO 2 (36.5), C 2 H 2 /C 2 H 4 (24.2), and C 2 H 2 /CH 4 (1312.9) separation at ambient conditions, respectively, of which the C 2 H 2 /CO 2 selectivity is the highest among all the robust MOFs reported so far. Theoretical calculations indicate that the oppositely adjacent nickel(II) centers together with cyanide groups from different layers in ZJU‐74a can construct a sandwich‐type adsorption site to offer dually strong and cooperative interactions for the C 2 H 2 molecule, thus leading to its ultrahigh C 2 H 2 capture capacity and selectivities. The exceptional separation performance of ZJU‐74a is confirmed by both simulated and experimental breakthrough curves for 50/50 (v/v) C 2 H 2 /CO 2 , 1/99 C 2 H 2 /C 2 H 4 , and 50/50 C 2 H 2 /CH 4 mixtures under ambient conditions.