光子上转换
光催化
光化学
材料科学
光致发光
可见光谱
电子顺磁共振
氧气
光电流
辐照
化学工程
化学
光电子学
兴奋剂
催化作用
核磁共振
有机化学
工程类
核物理学
物理
作者
Fangfang Duo,Yawen Wang,Caimei Fan,Xiaochao Zhang,Yunfang Wang
标识
DOI:10.1016/j.jallcom.2016.05.259
摘要
CQDs/BiOBr composites with oxygen vacancies were synthesized by a simple hydrolysis method at room temperature. The obtained composites exhibited much higher photocatalytic activity and stability than pure BiOBr under visible light. The upconversion effect of CQDs on BiOBr was studied by photoluminescence (PL) spectra, transient photocurrent (PC) responses measurements, electron spin resonance (ESR) analysis, reactive species scavenger experiments, and RhB and BPA degradation under monochromatic light irradiation. The results demonstrated that the upconversion effect of CQDs could improve O2− formation on BiOBr during photocatalytic process via more electron transfer in oxygen vacancies owing to the desirable long wavelength visible light and near infrared (NIR) light absorption property of CQDs. Moreover, the upconversion effect of CQDs could refresh the oxygen vacancies on BiOBr and therefore maintain the photocatalytic stability of BiOBr.
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