区域选择性
磷酸化
化学
联轴节(管道)
亲核细胞
协议(科学)
组合化学
芯(光纤)
立体化学
计算机科学
生物化学
材料科学
催化作用
电信
医学
病理
冶金
替代医学
作者
Soumyadip Hore,Abhijeet Singh,Ravi P. Singh
标识
DOI:10.1002/asia.202201224
摘要
A practical and straightforward protocol to access site-selective C-3 phosphorylated benzofulvenes by means of cross-dehydrogenative coupling of two nucleophilic moieties, employing silver as a promoter, is described here. Remarkably, this protocol provides a broad, structurally diverse phosphorylated benzofulvene. Initial mechanistic studies shed light on its radical coupling nature, and late-stage transformations offer highly diversified benzofulvenes core.
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