双功能
静电纺丝
材料科学
电池(电)
电极
阴极
纳米纤维
催化作用
电催化剂
化学工程
电化学
钴
氧化钴
析氧
克拉克电极
纳米颗粒
介质阻挡放电
双功能催化剂
纳米技术
化学
复合材料
冶金
光电子学
聚合物
电介质
有机化学
功率(物理)
量子力学
电解质
工程类
物理
物理化学
作者
Jian Zhou,Tong Liu,Jing Zhang,Ling Zhao,Wei He,Yao Wang
标识
DOI:10.1016/j.seppur.2022.122316
摘要
Rational design of efficient and stable bifunctional oxygen electrocatalyst is of significant importance for research and progress of rechargeable zinc-air battery (ZAB). Herein, ultrafine cobalt free perovskite type oxide Sr2Fe1.5Mo0.5O6-δ nanofibers (SFM NF) and SFM nanoparticles (SFM NP) have been prepared via the electrospinning technique and combustion technique, respectively, and their electrochemical behaviors in the field of ZAB have been studied. Our study demonstrates that SFM NF catalyst has better bifunctional electrocatalytic activities and more durable charge–discharge cycling stability than SFM NP catalyst. When used as cathode catalysts for ZABs, SFM NF electrode exhibits a higher peak power density of 137 mW cm−2 than 107.9 mW cm−2 for SFM NP electrode. In addition, SFM NF electrode presents a lower galvanostatic charge–discharge voltage gap (ΔE) of 0.94 V than 1.13 V for SFM NP electrode when operated at 10 mA cm−2, which can be explained by the enhanced bifunctional electrocatalytic activities. More importantly, SFM NF electrode presents a significantly low ΔE degradation rate of 0.01 V/100 h during the 300-hour operation, indicating its excellent change-discharge stability. Our findings indicate that SFM NF catalyst is a greatly promising cathode candidate of efficient and durable rechargeable ZAB, and the electrospinning technique is an effective strategy to prepare efficient electrocatalysts for energy storage and conversion application.
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