电致变色
电致变色装置
材料科学
涂层
超级电容器
固态
纳米技术
聚合物
光电子学
电极
复合材料
化学
电化学
物理化学
作者
Huan Ling,Junsen Zhang,Yu Wang,Xiping Zeng
标识
DOI:10.1016/j.jcis.2024.03.131
摘要
Electrochromic devices (ECD) are widely used to regulate the transmittance of sunlight by applying a small voltage, but the drawbacks like complex layer-by-layer preparation procedures and inconvenient assembling process still exists. To address these problems, gel or solution-type all-in-one ECDs were recently developed for the simple structure, however, the leakage risk and absence of flexible large-area production have limited real applications. Herein, a novel all-solid-state and all-in-one flexible ECD was reported by originally developed polymer dispersed electrochromic device (PDECD) strategy. This all-solid-state flexible ECD could be efficiently prepared only by one step of phase separation without any extra treatment, and demonstrated outstanding stability (92.1 % of original ΔT remained after 10,000 cycles), high coloration efficiency (197 cm2/C), low power consumption (86.4 μW/cm2) and satisfied response time (≤12 s). Meanwhile, the stored power in ECD during coloring process could drive a LED with excellent cyclic stability (93 % of original capacity remained after 3000 cycles), implying that ECD could also serve as an idea electrochromic supercapacitor. What'more, a reported largest viologen-based all-solid-state flexible ECD (17.8 × 13.2 cm2) with robust bending resistance (up to 1000 bending cycles) was successfully fabricated with industrial roller coating technique, which indicated the huge potential in real world.
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