Catalytic conversion of lignin into monoaromatic hydrocarbons over a Ni/Al hydrotalcite-derived catalyst

Lignin is the most abundant aromatic biopolymer. Thus, preparation of BTX (benzene, toluene and xylenes) by catalytic fast pyrolysis (CFP) of lignin is attractive. Ni-Al mixed metal oxide (MMO) catalysts, derived from pyrolyzing Ni-Al layered double hydroxides (LDH), were prepared for the catalytic fast pyrolysis of lignin. The effects of catalyst Ni/Al ratio, catalyst dosage and pyrolysis temperature on the liquid products were investigated by Py-GC/MS. The Ni3Al3-MMO produced the best liquid product distribution from lignin at 700 ℃. The selectivity of Ni3Al3-MMO for aliphatic hydrocarbons and monocyclic aromatic hydrocarbons (MAHs) was 18.0% and 78.2%, respectively. The selectivity to polyaromatic hydrocarbons (PAHs) was 3.8%. No phenols and phenolic derivatives were produced. This is related to the mesoporous catalytic structure (pore size of 14.37 nm), large external surface area (134.74 m2/g) and strong acidity (4.92 mmolNH3/g) of Ni3Al3-MMO. In addition, a mechanistic study was performed with the lignin model compound (guaiacol) showing that Ni3Al3-MMO exhibits strong deoxygenation activity for aromatic C–O bond cleavage of lignin.