Mechanism of selective lithium extraction from spent LiFePO4 cathodes in oxidizing alkaline leaching system

浸出(土壤学) 氧化剂 选择性浸出 还原剂 阴极 化学 环境污染 无机化学 材料科学 冶金 环境科学 环境保护 有机化学 物理化学 土壤科学 硫酸 土壤水分
作者
Wan Yang,Xiaojian Liu,Xiangyang Zhou,Jingjing Tang,Fanyun Su,Zhenxiao Li,Juan Yang,Yayun Ma
出处
期刊:Separation and Purification Technology [Elsevier]
卷期号:329: 125237-125237 被引量:3
标识
DOI:10.1016/j.seppur.2023.125237
摘要

Lithium-ion batteries (LIBs) usher in an explosive growth, but followed by many spent LIBs processing problems. Recycling the spent LIBs with both economic attributes and environmental benefits is imperative. However, the existing recycling processes have the problem of high cost, low efficiency and environmental pollution. In this study, NaOH is innovatively adopted as leaching agent for the hydrometallurgical recovery of spent LiFePO4 cathodes, realizing the efficiently selective lithium extraction without additional oxidizing agent addition. Meanwhile, Li3PO4 product is obtained by in-situ concentration of the leaching solution without adding precipitant, and Fe2O3 by-product can be obtained by leaching residue. Under the conditions of 2 mol/L NaOH, L/S ratio of 50:1 mL/g, 50 °C and 2 h, the leaching efficiencies of Li and P can reach 98.2 % and 99.9 %, and all of Fe is converted into Fe3O4. The kinetic study reveals that the leaching process is controlled by chemical reaction. Moreover, it is innovatively found that NaOH play the dual role of leaching agent and oxidant, and the Na+ may have intercalation effect on the structure of LiFePO4. Compared with traditional process, this method has the advantages of low cost, high efficiency and environmental friendliness.
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