材料科学
电流(流体)
电池(电)
电压
锂离子电池
降级(电信)
热的
介电谱
核工程
锂(药物)
分析化学(期刊)
功率(物理)
电化学
化学
电极
热力学
电气工程
物理化学
内分泌学
工程类
物理
医学
色谱法
作者
Fengyang Cai,Huawei Chang,Zhengbo Yang,Zhengkai Tu
标识
DOI:10.1016/j.apenergy.2023.122232
摘要
Preheating is an effective solution to the severe degradation of lithium-ion battery (LIB) performance at low temperatures. In this study, a bidirectional pulse-current preheating strategy for LIBs at low temperatures without external power is proposed, which involves the incorporation of a direct current/direct current converter and a series of resistances, inductances, and switches. The effects of ambient temperature, initial state of charge, and preheating strategy on the voltage and current evolution, heating rate, and heating efficiency are experimentally analysed in a climatic chamber, in addition to the effects of various preheating strategies on battery degradation. A comparative analysis is conducted using the classical pulse self-heating strategy. The results indicate that the bidirectional pulse-current preheating strategy enables preheating under an ambient temperature of −15 °C at a rate of 6.38 °C/min and affords a thermal efficiency of 31.9%. By contrast, the pulse heating method affords a heating rate of 3.46 °C/min and a thermal efficiency of 24.2%. As the battery temperature decreases, both the charge/discharge switching period and heating rate decrease, whereas the thermal efficiency and energy consumption ratio improve. No significant degradation occurs after 30 heating cycles, and the bidirectional pulse-current preheating strategy is demonstrated through capacity testing, incremental capacity curves, and electrochemical impedance spectroscopy testing. This study proposes a new approach for preheating LIBs internally and provides experimental evidence for a bidirectional-pulse preheating strategy.
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