化学
芳基
催化作用
镍
对偶(语法数字)
联轴节(管道)
组合化学
有机化学
烷基
机械工程
艺术
文学类
工程类
作者
Xu He,Shouxin Zhang,Jia‐Yi Shou,Lingling Chu,Feng‐Ling Qing
出处
期刊:Organic Letters
[American Chemical Society]
日期:2024-07-31
卷期号:26 (31): 6782-6786
标识
DOI:10.1021/acs.orglett.4c02553
摘要
Herein we report a photoredox/nickel-catalyzed cross-coupling of aryl bromides with 1,1,1,3,3,3-hexafluoroisopropanol for the construction of hexafluoroisopropyl aryl ethers. The mild reaction conditions employed allow for the applicability of a wide range of aryl and heteroaryl bromides. Late-stage functionalization and preliminary mechanistic studies have been demonstrated.
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