煅烧
材料科学
吸附
比表面积
纳米颗粒
多孔性
化学工程
纳米技术
选择性
降水
催化作用
化学
物理化学
有机化学
复合材料
物理
工程类
气象学
作者
Shuang Liang,Dandan Wu,Huiru Zhang,Liling Liu,Chugeng Huang,Guojian Jiang
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2023-05-01
卷期号:170 (5): 057514-057514
被引量:1
标识
DOI:10.1149/1945-7111/acd4f3
摘要
Recently, field effect transistor type N,N-dimethylformamide (DMF) sensors have been widely studied, but semiconductor resistance type DMF gas sensors have not been reported much. Herein, porous LaFeO 3 nanoparticles were prepared by reverse co-precipitation, and the gas sensing detection performance of material was studied. The sensor based on LaFeO 3 calcined at 750 °C shows excellent response (R g /R a = 189.2), great selectivity and long-term stability to 100 ppm DMF at the operating temperature of 170 °C. The effects of different calcination temperatures (650 °C, 750 °C, 900 °C) on the structure and properties of LaFeO 3 were compared. The structural characterization data revealed that LaFeO 3 calcined at 750 °C has the appropriate specific surface area and abundant active sites, which plays a key role in promoting the adsorption and decomposition of target gas. In addition, the surface of the LaFeO 3 calcined at 750 °C has the highest concentration of adsorbed oxygen, which also provides an excellent condition for gas-sensitive reactions on the surface of the material. Therefore, LaFeO 3 is expected to be a potential novel material in DMF detection.
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