Utilization of nitrogen, sulfur co-doped porous carbon micron spheres as bifunctional electrocatalysts for electrochemical detection of cadmium, lead and mercury ions and oxygen evolution reaction

双功能 析氧 过电位 电催化剂 无机化学 化学 碳纤维 硫黄 催化作用 电化学 材料科学 电极 有机化学 物理化学 复合材料 复合数
作者
Huiyu Li,Na Li,Pingping Zuo,Shijie Qu,Fangfang Qin,Wenzhong Shen
出处
期刊:Journal of Colloid and Interface Science [Elsevier BV]
卷期号:640: 391-404 被引量:14
标识
DOI:10.1016/j.jcis.2023.02.125
摘要

The development of high-performance bifunctional electrocatalysts for oxygen evolution reaction and heavy metal ion (HMI) detection is significant and challenging. Here, a novel nitrogen, sulfur co-doped porous carbon sphere bifunctional catalyst was designed and fabricated by hydrothermal followed by carbonization using starch as carbon source and thiourea as nitrogen, sulfur source for HMI detection and oxygen evolution reactions. Under the synergistic effect of pore structure, active sites and nitrogen, sulfur functional groups, C-S0.75-HT-C800 demonstrated excellent HMI detection performance and oxygen evolution reaction activity. Under optimized conditions, the detection limits (LODs) of C-S0.75-HT-C800 sensor were 3.90, 3.86 and 4.91 nM for Cd2+, Pb2+ and Hg2+ when detected individually; and the sensitivities were 13.12, 19.50 and 21.19 μA/μM. The sensor also obtained high recoveries of Cd2+, Hg2+ and Pb2+ in river water samples. During the oxygen evolution reaction, a Tafel slope of 70.1 mV/dec and a low overpotential of 277 mV were obtained for C-S0.75-HT-C800 electrocatalyst with a current density of 10 mA/cm2 in basic electrolyte. This research offers a neoteric and simple strategy in the design as well as fabrication of bifunctional carbon-based electrocatalysts.
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