材料科学
催化作用
纳米颗粒
化学工程
铟
氧化物
光催化
氮气
硫黄
纳米技术
碳纤维
化学
有机化学
复合材料
光电子学
冶金
工程类
复合数
作者
Liming Sun,Rong Li,Wenwen Zhan,Yusheng Yuan,Xiaojun Wang,Xiguang Han,Yanli Zhao
标识
DOI:10.1038/s41467-019-10302-0
摘要
Abstract Excellent catalytic activity, high stability and easy recovery are three key elements for fabricating efficient photocatalysts, while developing a simple method to fabricate such photocatalysts with these three features at the same time is highly challenging. In this study, we successfully synthesized double-shelled hollow rods (DHR) assembled by nitrogen (N) and sulfur (S)-codoped carbon coated indium(III) oxide (In 2 O 3 ) ultra-small nanoparticles (N,S-C/In 2 O 3 DHR). N,S-C/In 2 O 3 DHR exhibits remarkable photocatalytic activity, high stability and easy recovery for oxidative hydroxylation reaction of arylboronic acid substrates. The catalyst recovery and surface area were well balanced through improved light harvesting, contributed by concurrently enhancing the reflection on the outer porous shell and the diffraction in the inside double-shelled hollow structure, and increased separation rate of photogenerated carriers. Photocatalytic mechanism was investigated to identify the main reactive species in the catalytic reactions. The electron separation and transfer pathway via N,S-codoped graphite/In 2 O 3 interface was revealed by theoretical calculations.
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