纳米棒
光催化分解水
可见光谱
材料科学
单晶
氢
半导体
结晶学
光化学
分解水
纳米技术
化学工程
光电子学
化学
光催化
生物化学
工程类
催化作用
有机化学
作者
Zheng Wang,Yasunobu Inoue,Takashi Hisatomi,Ryo Ishikawa,Qian Wang,Tsuyoshi Takata,Shanshan Chen,Naoya Shibata,Yuichi Ikuhara,Kazunari Domen
出处
期刊:Nature Catalysis
[Springer Nature]
日期:2018-08-31
卷期号:1 (10): 756-763
被引量:435
标识
DOI:10.1038/s41929-018-0134-1
摘要
Although one-step-excitation overall water splitting on a particulate photocatalyst is a simple means of performing scalable solar-to-hydrogen energy conversion, there is a lack of photocatalysts with significant activity under visible light. Despite its superior visible-light absorption, the Ta3N5 photocatalyst has not accomplished overall water splitting due to strong charge recombination at defects. Here, we show rapid growth of Ta3N5 nanorods on lattice-matched cubic KTaO3 particles through the volatilization of potassium species during a brief nitridation process. The Ta3N5 nanorods generated selectively on the edge of KTaO3 are spatially separated and well-defined single crystals free from grain boundaries. When combined with the Rh/Cr2O3 co-catalyst, the single-crystal Ta3N5 nanorods split water into hydrogen and oxygen very efficiently under visible light and simulated sunlight. Our findings demonstrate the importance of nanostructured single-crystal photocatalysts free from structural defects in solar water splitting. Ta3N5 is a semiconductor with very promising photocatalytic properties. However, performing overall water splitting with this material has remained elusive. Now, Domen and co-workers report a method for the synthesis of defect-free single-crystal Ta3N5 nanorods capable of splitting water into hydrogen and oxygen in the presence of a co-catalyst.
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