Overall water splitting by Ta3N5 nanorod single crystals grown on the edges of KTaO3 particles

纳米棒 光催化分解水 可见光谱 材料科学 单晶 半导体 结晶学 光化学 分解水 纳米技术 化学工程 光电子学 化学 光催化 生物化学 工程类 催化作用 有机化学
作者
Zheng Wang,Yasunobu Inoue,Takashi Hisatomi,Ryo Ishikawa,Qian Wang,Tsuyoshi Takata,Shanshan Chen,Naoya Shibata,Yuichi Ikuhara,Kazunari Domen
出处
期刊:Nature Catalysis [Springer Nature]
卷期号:1 (10): 756-763 被引量:435
标识
DOI:10.1038/s41929-018-0134-1
摘要

Although one-step-excitation overall water splitting on a particulate photocatalyst is a simple means of performing scalable solar-to-hydrogen energy conversion, there is a lack of photocatalysts with significant activity under visible light. Despite its superior visible-light absorption, the Ta3N5 photocatalyst has not accomplished overall water splitting due to strong charge recombination at defects. Here, we show rapid growth of Ta3N5 nanorods on lattice-matched cubic KTaO3 particles through the volatilization of potassium species during a brief nitridation process. The Ta3N5 nanorods generated selectively on the edge of KTaO3 are spatially separated and well-defined single crystals free from grain boundaries. When combined with the Rh/Cr2O3 co-catalyst, the single-crystal Ta3N5 nanorods split water into hydrogen and oxygen very efficiently under visible light and simulated sunlight. Our findings demonstrate the importance of nanostructured single-crystal photocatalysts free from structural defects in solar water splitting. Ta3N5 is a semiconductor with very promising photocatalytic properties. However, performing overall water splitting with this material has remained elusive. Now, Domen and co-workers report a method for the synthesis of defect-free single-crystal Ta3N5 nanorods capable of splitting water into hydrogen and oxygen in the presence of a co-catalyst.
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