塞贝克系数
电阻率和电导率
凝聚态物理
材料科学
化学计量学
铁磁性
大气温度范围
热电效应
晶体结构
热导率
结晶学
化学
热力学
物理
物理化学
量子力学
复合材料
作者
Jaćim Jaćimović,Petar Popčević,Alla Arakcheeva,P. Pattison,A. Pisoni,S. Katrych,Krunoslav Prša,H. Berger,Ana Smontara,L. Forró
标识
DOI:10.1016/j.jallcom.2019.04.159
摘要
Single crystal growth by chemical vapour transport has resulted samples with Fe1.35Ge stoichiometry. Structural study has shown that the large number of vacancies introduces an incommensuately modulated structure. The electrical resistivity is in the 200 μΩcm range at room temperature, and although the ferromagnetic transition temperature at 425 K is clearly visible, it hardly varies down to 4.2 K. It is suggested that the large number of vacancies (and the incommensurate modulation) introduce a strong backscattering, and the system is at the brink of a Mooij correlation. The thermal conductivity and Seebeck coefficient carry also the consequences of the high concentration of vacancies.
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