Silicalite-1 zeolite acidification by zinc modification and its catalytic properties for isobutane conversion

异丁烷 沸石 催化作用 化学 无机化学 化学工程 有机化学 工程类
作者
Guodong Liu,Jiaxu Liu,Ning He,Cuilan Miao,Jilei Wang,Qin Xin,Hongchen Guo
出处
期刊:RSC Advances [Royal Society of Chemistry]
卷期号:8 (33): 18663-18671 被引量:32
标识
DOI:10.1039/c8ra02467g
摘要

A series of Zn-modified Silicalite-1 (S-1) zeolites (Zn x /S-1) were prepared by the wetness-impregnation method and applied in the catalytic conversion of isobutane. The structure and location of Zn species in Zn x /S-1 were investigated using UV-Vis and N2 physical adsorption. The acidity and origin of the acid sites in Zn x /S-1 were studied by NH3-temperature programmed desorption and Fourier-transform infrared analysis. The catalytic performance of Zn x /S-1 for isobutane conversion was investigated in a fixed-bed microreactor. In the experiments, the acidity of S-1 zeolite was dramatically increased by modification with Zn, with both Lewis and Brønsted sites identified in Zn x /S-1. The relationship between Brønsted acid sites and Zn-OH groups on ZnO clusters of Zn x /S-1 was also revealed for the first time. Furthermore, Zn x /S-1 catalysts exhibited excellent catalytic performances in both isobutane dehydrogenation and butene isomerization reactions. A high selectivity of total butene products ranging from 84.6 to 97.2 was achieved on the catalysts with different Zn loadings. Moreover, the linear correlation between isobutane conversion and the acid amount (determined by NH3-TPD) confirmed that the weak-to-medium acid sites in Zn x /S-1 should play a key role in isobutane conversion.
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