Pure water leaching soluble manganese from electrolytic manganese residue: Leaching kinetics model analysis and characterization

浸出(土壤学) 阿累尼乌斯方程 活化能 化学 无机化学 材料科学 冶金 地质学 有机化学 土壤科学 土壤水分
作者
Zheng Fan,Hua Zhu,Teng Luo,Haojie Wang,Haobo Hou
出处
期刊:Journal of environmental chemical engineering [Elsevier BV]
卷期号:8 (4): 103916-103916 被引量:55
标识
DOI:10.1016/j.jece.2020.103916
摘要

Electrolytic manganese residue (EMR) is a solid waste that generated in electrolytic manganese metal production, which would not only contaminate the environment due it contains soluble manganese, but occupy a large amount of farmlands as well. Hence, recovering manganese from EMR using economical method is the key to achieve the targets of resource recycling and solid waste harmless treatment. In this paper, pure water was used to leach soluble manganese out from EMR. Leaching kinetics model of manganese were established and examined, characteristics of EMR before and after leaching were analyzed by XRF, XRD, EPMA-WDS and SEM. The results revealed that the apparent activated energy (E) during the leaching processes was 11.17 ± 2.02 kJ/mol and the slope in fitting line of Arrhenius equation was −1.343, which indicated that the leaching kinetic model was appropriate and the rate determining step was diffusion process, that is, Mn2+ migrate into bulk solution from diffusion layer. The main crystal phases in EMR are quartz (SiO2) and calcium sulfate (CaSO4·nH2O) (n = 0.5 or 2), but the distribution relationship between SiO2 and CaSO4·nH2O was not regular. Mn is in the form of “film” covered in CaSO4 bar in EMR. High temperature and high volume of water could promote Mn2+ transport process. The optimal leaching condition was S:L (Solid : Liquid)1:4, temperature was 24 °C and the agitation rate was 300 r/min when combined the cost and efficiency, and 83.35 % soluble manganese can be leached out from EMR.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
butterfly发布了新的文献求助10
刚刚
豆豆完成签到 ,获得积分10
1秒前
范先生完成签到,获得积分10
4秒前
2222222完成签到,获得积分10
4秒前
Hello应助bulingbuling采纳,获得10
4秒前
蜡笔小新完成签到,获得积分10
7秒前
希望天下0贩的0应助小王采纳,获得10
7秒前
赘婿应助lh采纳,获得10
8秒前
8秒前
科研通AI2S应助butterfly采纳,获得10
9秒前
大模型应助butterfly采纳,获得10
9秒前
11秒前
做个梦给你完成签到,获得积分10
11秒前
学霸宇大王完成签到 ,获得积分10
11秒前
甜蜜的楷瑞完成签到,获得积分10
12秒前
魏煜佳完成签到,获得积分10
13秒前
Lc完成签到,获得积分10
13秒前
三伏天完成签到,获得积分10
13秒前
清图完成签到,获得积分10
13秒前
英姑应助简单采纳,获得10
13秒前
爱喝牛奶的大兔子完成签到 ,获得积分20
14秒前
15秒前
15秒前
潇湘雪月完成签到,获得积分10
16秒前
迎南完成签到,获得积分10
16秒前
懒癌晚期完成签到,获得积分10
17秒前
17秒前
初夏微凉发布了新的文献求助10
17秒前
17秒前
18秒前
19秒前
乐乐应助科研通管家采纳,获得10
20秒前
深情安青应助科研通管家采纳,获得10
20秒前
赘婿应助科研通管家采纳,获得10
20秒前
英姑应助科研通管家采纳,获得10
20秒前
田様应助科研通管家采纳,获得10
20秒前
所所应助科研通管家采纳,获得10
20秒前
英俊的铭应助科研通管家采纳,获得10
20秒前
烟花应助科研通管家采纳,获得10
20秒前
上官若男应助科研通管家采纳,获得10
20秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
Research on Disturbance Rejection Control Algorithm for Aerial Operation Robots 500
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038388
求助须知:如何正确求助?哪些是违规求助? 3576106
关于积分的说明 11374447
捐赠科研通 3305798
什么是DOI,文献DOI怎么找? 1819322
邀请新用户注册赠送积分活动 892672
科研通“疑难数据库(出版商)”最低求助积分说明 815029