析氧
电催化剂
电化学
氧气
扩散
图灵
材料科学
化学
化学物理
电极
计算机科学
热力学
物理化学
物理
有机化学
程序设计语言
作者
Xiaolong Zhang,Peng‐Peng Yang,Ya‐Rong Zheng,Yu Duan,Shao‐Jin Hu,Tao Ma,Fei‐Yue Gao,Zhuang‐Zhuang Niu,Zhi‐Zheng Wu,Qin Shuai,Li‐Ping Chi,Xingxing Yu,Rui Wu,Chao Gu,Chengming Wang,Xusheng Zheng,Xiao Zheng,Junfa Zhu,Min‐Rui Gao
标识
DOI:10.1002/anie.202017016
摘要
Abstract Although the Turing structures, or stationary reaction‐diffusion patterns, have received increasing attention in biology and chemistry, making such unusual patterns on inorganic solids is fundamentally challenging. We report a simple cation exchange approach to produce Turing‐type Ag 2 Se on CoSe 2 nanobelts relied on diffusion‐driven instability. The resultant Turing‐type Ag 2 Se‐CoSe 2 material is highly effective to catalyze the oxygen evolution reaction (OER) in alkaline electrolytes with an 84.5 % anodic energy efficiency. Electrochemical measurements show that the intrinsic OER activity correlates linearly with the length of Ag 2 Se‐CoSe 2 interfaces, determining that such Turing‐type interfaces are more active sites for OER. Combing X‐ray absorption and computational simulations, we ascribe the excellent OER performance to the optimized adsorption energies for critical oxygen‐containing intermediates at the unconventional interfaces.
科研通智能强力驱动
Strongly Powered by AbleSci AI