Synthesis and evaluation of an environment‐friendly terpolymer CaCO3 scale inhibitor for oilfield produced water with better salt and temperature resistance

ABSTRACT The CaCO 3 deposits exist widely in the petroleum industry, causing severe damage to the equipment and production. In this article, a novel environment‐friendly terpolymer scale inhibitor Poly (maleic anhydride ‐ acrylic acid ‐2‐ acrylamide ‐2‐ methyl propanesulfonic acid) (P(MA‐AA‐AMPS))‐containing carboxylic acid group, sulfonic acid group, and amide group was synthesized. The structure and molecular weight were characterized by FTIR, 1 H‐NMR, and GPC. The static scale inhibition experiment was conducted to study the influence of factors such as the dosage, monomer ratio, temperature, pH, Ca 2+ concentration, and concentration on the scale inhibition performance of CaCO 3 . The results show that when the monomer ratio is 2.0:1.0:0.5 and the dosage is 20 mg L −1 , the maximum scale inhibition efficiency is 95.52%. Even when Ca 2+ concentration exceeds 1200 mg L −1 and temperature reaches 90 °C, the scale inhibition efficiency is still larger than 80%. The results of SEM and XRD show that P(MA‐AA‐AMPS) interferes with the growth of CaCO 3 crystal by adsorption, dispersion, and chelation. The effect leads to changes in the morphology of CaCO 3 crystals, the size of which drops from 20–30 μm to 2–5 μm. The P(MA‐AA‐AMPS) can transform CaCO 3 from stable calcite crystals to unstable aragonite and vaterite. Finally, the formation of CaCO 3 scale is well inhibited. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137 , 48460.