Cooperative Catalysis through Noncovalent Interactions

Angewandte Chemie International EditionVolume 52, Issue 6 p. 1668-1672 Communication Cooperative Catalysis through Noncovalent Interactions† Dr. Weijun Tang, Dr. Weijun Tang Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiao These authors contributed equally to this work.Search for more papers by this authorSteven Johnston, Steven Johnston Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiao These authors contributed equally to this work.Search for more papers by this authorDr. Jonathan A. Iggo, Corresponding Author Dr. Jonathan A. Iggo Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoLiverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorDr. Neil G. Berry, Dr. Neil G. Berry Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorDr. Marie Phelan, Dr. Marie Phelan NMR Centre for Structural Biology, Institute of Integrative Biology, University of Liverpool, Liverpool, L69 7ZB (UK)Search for more papers by this authorProf. Luyun Lian, Prof. Luyun Lian NMR Centre for Structural Biology, Institute of Integrative Biology, University of Liverpool, Liverpool, L69 7ZB (UK)Search for more papers by this authorDr. John Bacsa, Dr. John Bacsa Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorProf. Jianliang Xiao, Corresponding Author Prof. Jianliang Xiao [email protected] Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoLiverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this author Dr. Weijun Tang, Dr. Weijun Tang Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiao These authors contributed equally to this work.Search for more papers by this authorSteven Johnston, Steven Johnston Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiao These authors contributed equally to this work.Search for more papers by this authorDr. Jonathan A. Iggo, Corresponding Author Dr. Jonathan A. Iggo Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoLiverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorDr. Neil G. Berry, Dr. Neil G. Berry Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorDr. Marie Phelan, Dr. Marie Phelan NMR Centre for Structural Biology, Institute of Integrative Biology, University of Liverpool, Liverpool, L69 7ZB (UK)Search for more papers by this authorProf. Luyun Lian, Prof. Luyun Lian NMR Centre for Structural Biology, Institute of Integrative Biology, University of Liverpool, Liverpool, L69 7ZB (UK)Search for more papers by this authorDr. John Bacsa, Dr. John Bacsa Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorProf. Jianliang Xiao, Corresponding Author Prof. Jianliang Xiao [email protected] Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoLiverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this author First published: 03 January 2013 https://doi.org/10.1002/anie.201208774Citations: 83 † We thank EPRSC for funding support to W.J.T. and S.J. on grant EP/G031444, the University of Liverpool for support of the NMR Centre for Structural Biology, and the EPSRC National Mass Spectrometry Service Centre for mass analysis. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract One of four: A chiral phosphoric acid enables asymmetric hydrogenation of imines with an achiral iridium catalyst by virtue of noncovalent interactions. These interactions lead to the formation of a highly organized ternary complex, and the hydride is transferred highly enantioselectively. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201208774_sm_miscellaneous_information.pdf3.4 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1a Organocatalysis (Eds.: ), Springer, Berlin, 2008; Google Scholar 1bR. R. Knowles, E. N. Jacobsen, Proc. Natl. Acad. Sci. USA 2010, 107, 20678–20685. 10.1073/pnas.1006402107 CASPubMedWeb of Science®Google Scholar 2For examples, see: Google Scholar 2aM. Yamakawa, I. Yamada, R. Noyori, Angew. Chem. 2001, 113, 2900–2903; 10.1002/1521-3757(20010803)113:15<2900::AID-ANGE2900>3.0.CO;2-8 Google ScholarAngew. 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