摘要
Angewandte Chemie International EditionVolume 52, Issue 6 p. 1668-1672 Communication Cooperative Catalysis through Noncovalent Interactions† Dr. Weijun Tang, Dr. Weijun Tang Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiao These authors contributed equally to this work.Search for more papers by this authorSteven Johnston, Steven Johnston Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiao These authors contributed equally to this work.Search for more papers by this authorDr. Jonathan A. Iggo, Corresponding Author Dr. Jonathan A. Iggo Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoLiverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorDr. Neil G. Berry, Dr. Neil G. Berry Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorDr. Marie Phelan, Dr. Marie Phelan NMR Centre for Structural Biology, Institute of Integrative Biology, University of Liverpool, Liverpool, L69 7ZB (UK)Search for more papers by this authorProf. Luyun Lian, Prof. Luyun Lian NMR Centre for Structural Biology, Institute of Integrative Biology, University of Liverpool, Liverpool, L69 7ZB (UK)Search for more papers by this authorDr. John Bacsa, Dr. John Bacsa Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorProf. Jianliang Xiao, Corresponding Author Prof. Jianliang Xiao [email protected] Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoLiverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this author Dr. Weijun Tang, Dr. Weijun Tang Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiao These authors contributed equally to this work.Search for more papers by this authorSteven Johnston, Steven Johnston Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiao These authors contributed equally to this work.Search for more papers by this authorDr. Jonathan A. Iggo, Corresponding Author Dr. Jonathan A. Iggo Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoLiverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorDr. Neil G. Berry, Dr. Neil G. Berry Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorDr. Marie Phelan, Dr. Marie Phelan NMR Centre for Structural Biology, Institute of Integrative Biology, University of Liverpool, Liverpool, L69 7ZB (UK)Search for more papers by this authorProf. Luyun Lian, Prof. Luyun Lian NMR Centre for Structural Biology, Institute of Integrative Biology, University of Liverpool, Liverpool, L69 7ZB (UK)Search for more papers by this authorDr. John Bacsa, Dr. John Bacsa Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this authorProf. Jianliang Xiao, Corresponding Author Prof. Jianliang Xiao [email protected] Liverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoLiverpool centre for Materials & Catalysis, Department of Chemistry, University of Liverpool, Liverpool L69 7ZD (UK) http://pcwww.liv.ac.uk/∼xiaoSearch for more papers by this author First published: 03 January 2013 https://doi.org/10.1002/anie.201208774Citations: 83 † We thank EPRSC for funding support to W.J.T. and S.J. on grant EP/G031444, the University of Liverpool for support of the NMR Centre for Structural Biology, and the EPSRC National Mass Spectrometry Service Centre for mass analysis. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract One of four: A chiral phosphoric acid enables asymmetric hydrogenation of imines with an achiral iridium catalyst by virtue of noncovalent interactions. These interactions lead to the formation of a highly organized ternary complex, and the hydride is transferred highly enantioselectively. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. 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