过电位
电压降
电压
欧姆接触
化学
电解
重力流
机械
材料科学
物理
电流(流体)
热力学
电化学
电极
电解质
物理化学
内波
量子力学
作者
Mingyong Wang,Zhi Wang,Zhancheng Guo
标识
DOI:10.1016/j.ijhydene.2010.01.128
摘要
Water electrolysis was carried out galvanostatically under a super gravity field. The relationships of cell voltage, ohmic voltage drop reduction and overpotential reduction with gravity coefficient (G) and current densities were studied. It was found that water electrolysis was noticeably enhanced by the super gravity field. Good linear relationships between cell voltage (U) and logarithm of G can be obtained at all current densities. Large cell voltage reduction was achieved under the super gravity field, especially under higher gravity and at higher current densities. Energy savings were about 9–17% at 0.5 A cm−2 under the super gravity field. The cell voltage reduction was ascribed to ohmic voltage drop reduction and overpotential reduction. The share of ohmic voltage drop reduction (iΔRG) in cell voltage reduction (ΔUG) was higher than 70% at all current densities. At constant cell voltage, the rate of hydrogen produced under super gravity field increased noticeably compared to that under normal gravity condition.
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