化学
超分子化学
结晶学
氢键
羧酸盐
正交晶系
单斜晶系
氢铵
分子
晶体结构
发光
配体(生物化学)
立体化学
有机化学
物理
受体
生物化学
光电子学
作者
Qingqing Zhang,Zhi‐Hui Zhang,Bao-Hua Qu,Qun Chen,Ming‐Yang He
标识
DOI:10.1016/j.ica.2014.04.006
摘要
N-(2-Pyridylmethyl)-l-alanine (l-Hpana), and N-(2-pyridylmethyl)-aspartic acid (l-H2pasp) have been solvothermally prepared and structurally characterized by X-ray single-crystal diffraction. Complexes 1 and 2 crystallize in the monoclinic P21/c and orthorhombic C2221 space groups, respectively, due to the dissimilar ligand features (chirality of l-Hpana). They show similar mononuclear coordination structures with two kinds of five-member chelating rings, which are assembled into 2D supramolecular networks through multiple N–H⋯O and O–H⋯O interactions. For complex 3, the formation of a Ni–O bond between Ni(II) and the side-chain carboxylate lead to a left-handed helical coordination polymer with helical water chains inclusion. The most striking feature is that the helical hydrogen-bonding motif represents rare hydrated hydronium aggregation that formed by strong interactions between hydronium ions and guest water molecules. This helical aggregate is further stabilized by multiple hydrogen bonds with other lattice water molecules and chloride counteranions. The thermal and luminescent properties of these complexes have also been investigated.
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