Isotopes and geochemistry in a managed aquifer recharge scheme: a case study of fresh water injection at the Damascus University Campus, Syria

Abstract A combination of stable isotopes ( 18 O and 2 H) and hydrochemistry has been applied to investigate storage processes in relation to aquifer storage and recovery (ASR) of the shallow alluvial Quaternary aquifer in Damascus basin. The stored water, entirely taken from the Figeh springs during flood periods, was injected in a single well having a brackish groundwater. Water samples were collected from four observation wells drilled in the Damascus University Campus (DUC) site during a 3‐year period (2006–2008). The injectant water, which deviates in its chemical and isotopic signatures from that of the ambient groundwater, shows that the stored water plume remains within close proximity to the injection well (IW) (<≈ 100 m). Thus, only two wells (W13 and W14) located at a distance less than 80 m from the injection point were affected by this injection. The observation wells located at longer distances from the IW (≈145 m and ≈ 600 m for wells W15 and WHz, respectively) were completely unaffected by the injection. Although most of the chemical and isotopic parameters usefully reflected the mixing process that occurs between the injectant water and ambient groundwater, the stable isotope ( 18 O) and chloride (Cl − ) were the most sensitive parameters that quickly reflect this signature. Using a simple mass balance, the calculated proportion of injectant water reaching the well W13 was in the range of 50–90%. This proportion was even lower (30–55%) in the case of well W14. Although the drought event prevailing during this study did not much help to inject further amounts of water, higher than the injected volume (0·2416 M m 3 ) and also not favourable to better evaluate the fate and subsurface hydrological processes, these findings offer encouragement to continue the ASR activities, as an alternative way for better management of water resources in this basin facing intensive problems. Copyright © 2010 John Wiley & Sons, Ltd.