容量损失
电解质
电极
锂(药物)
降级(电信)
电化学
石墨
材料科学
电池(电)
扩散
自行车
相间
化学分解
分解
化学工程
复合材料
热力学
工程类
物理
化学
电气工程
有机化学
医学
生物
遗传学
考古
内分泌学
历史
物理化学
功率(物理)
作者
Rutooj D. Deshpande,Mark W. Verbrugge,Yang‐Tse Cheng,John Wang,Ping Liu
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2012-01-01
卷期号:159 (10): A1730-A1738
被引量:316
摘要
Coupled mechanical-chemical degradation of electrodes upon charging and discharging has been recognized as a major failure mechanism in lithium ion batteries. The instability of commonly employed electrolytes results in solid electrolyte interphase (SEI) formation. Although the SEI layer is necessary, as it passivates the electrode-electrolyte interface from further solvent decomposition, SEI formation consumes lithium and thus contributes to irreversible capacity loss. In this paper, we study irreversible capacity loss in a graphite-LiFePO4 cell. Our results support the mechanism of irreversible capacity loss due to the consumption of lithium in forming SEI. We attribute irreversible capacity loss to diffusion induced stresses (DISs) that cause pre-existing cracks on the electrode surfaces to grow gradually upon cycling, leading to the growth of SEI on the newly exposed electrode surfaces. Because lithium is consumed in forming the new SEI, irreversible capacity loss continues with cycling. Along with the SEI formation upon newly exposed (cracked) surfaces, the existing SEI thickness also grows with cycling, resulting in additional loss of lithium. In this study, we provide, a simple mathematical model, based on the Paris' Law formulation of mechanical fatigue, in combination with chemical degradation to explain battery life. We compare the predicted capacity at different temperatures with the experimental data obtained from electrochemical measurements on graphite-LiFePO4 cells.
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