材料科学
粘弹性
粘塑性
应力松弛
复合材料
应变率
磁滞
放松(心理学)
压力(语言学)
形状记忆聚合物
形状记忆合金
聚合物
蠕动
热力学
本构方程
有限元法
心理学
社会心理学
物理
语言学
哲学
量子力学
作者
Xiang Chen,Thao D. Nguyen
标识
DOI:10.1016/j.mechmat.2011.01.001
摘要
This work investigated the influence of material properties and loading conditions on the recovery performance of amorphous shape memory polymers using a recently developed thermoviscoelastic model. The model incorporated the time-dependent mechanisms of stress and structural relaxation and viscoplastic flow to describe the glass transition of the material from a soft viscoelastic rubber to a hard viscoplastic glass. The model captured many important features of the unconstrained strain recovery response and of the stress hysteresis observed in the constrained recovery response. A parameter study was developed that varied the model and loading parameters one-by-one to compare their effects on the start and end temperatures and recovery rate of the unconstrained recovery response and on the stress hysteresis of the constrained recovery response. The loading parameters included the cooling rate, the annealing time, and the high and low temperatures of the programming stage and the heating rate of the recovery stage. The results confirmed experimental observations that viscoelasticity is the underlying mechanism of the unconstrained recovery response. In contrast, the constrained recovery response was influenced by the interaction of many different mechanisms, including thermal expansion and structural and stress relaxation. For the loading parameters, the cooling rate of the programming stage and the heating rate of the recovery stage had the largest influence on both the constrained and unconstrained recovery response.
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