离子液体
溶剂
化学
胺气处理
离子键合
极地的
盐(化学)
二氧化碳
无机化学
大气(单位)
有机化学
酒
氮气
基础(拓扑)
氩
化学工程
离子
催化作用
数学分析
物理
数学
天文
工程类
热力学
作者
Philip G. Jessop,David J. Heldebrant,Xiaowang Li,Charles A. Eckert,Charles L. Liotta
出处
期刊:Nature
[Nature Portfolio]
日期:2005-08-01
卷期号:436 (7054): 1102-1102
被引量:914
摘要
Imagine a smart solvent that can be switched reversibly from a liquid with one set of properties to another that has very different properties, upon command. Here we create such a system, in which a non-ionic liquid (an alcohol and an amine base) converts to an ionic liquid (a salt in liquid form) upon exposure to an atmosphere of carbon dioxide, and then reverts back to its non-ionic form when exposed to nitrogen or argon gas. Such switchable solvents should facilitate organic syntheses and separations by eliminating the need to remove and replace solvents after each reaction step.
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