镧系元素
化学
纳米团簇
镝
原位
结晶学
冷凝
镧
离子
光化学
无机化学
有机化学
物理
热力学
作者
Jin-Mei Peng,Hai‐Ling Wang,Zhong‐Hong Zhu,Juan Bai,Fu‐Pei Liang,Zhong‐Hong Zhu
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2022-04-13
卷期号:61 (16): 6094-6100
被引量:20
标识
DOI:10.1021/acs.inorgchem.2c00221
摘要
A three-dimensional supermolecule structure is easily formed due to the diverse coordination modes of high-oxidation-state lanthanide metal ions. However, the design and construction of zero-dimensional (0 D) dish-shaped high-nuclearity lanthanide clusters are difficult. Herein, for the first time, we synthesized a series of the largest dish-shaped high-nuclearity lanthanide nanoclusters (1-4) by in situ tandem reactions under solvothermal one-pot conditions. The formation of 1 and 2 involved an in situ reaction of aldehydes and amines, while the condensation reactions between aldehydes occurred in 3 and 4. Based on the structural characteristics of the dish-shaped lanthanide clusters, we proposed two possible assembly mechanisms involving Dy1 → Dy7 → Dy13 → Dy19 (planar epitaxial growth mechanism) and Dy1 → Dy12 → Dy18 → Dy19 (planar internal growth mechanism).
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