光催化
激进的
烷基
化学
光化学
催化作用
氧化还原
电子转移
组合化学
有机化学
光催化
作者
Sandeep Patel,Biprajit Paul,Hrishikesh Paul,Rajat Shankhdhar,Indranil Chatterjee
摘要
A method for generating alkyl radicals using visible-light photoredox catalysis is described. This procedure was found to present an efficient means to access a diverse collection of 1°, 2°, and 3° alkyl radicals through the single-electron transfer of sulfones under mild reaction conditions. These alkyl radicals generated via the reductive desulfonylation of readily synthesized and stable alkylsulfones were engaged to forge C-C bonds. A detailed study was also carried out to shed light on the mechanism.
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