催化作用
4-硝基苯酚
钯
水溶液
抗坏血酸
稳定器(航空)
钴
硝基苯酚
纳米颗粒
扫描电子显微镜
材料科学
透射电子显微镜
双水相体系
选择性催化还原
氢氧化物
相(物质)
化学工程
化学
核化学
无机化学
纳米技术
有机化学
复合材料
工程类
机械工程
食品科学
作者
Zengmin Tang,Ling Zhang,Jingjing Du,Li-jian XU
标识
DOI:10.1016/s1003-6326(22)65925-9
摘要
Palladium-supported cobalt hydroxide (Co(OH)2-Pd) nanoplates were fabricated in an aqueous solution and employed as a catalyst for the reduction of 4-nitrophenol. For the preparation of Co(OH)2-Pd, Pd nanoparticles were anchored on the Co(OH)2 nanoplates after the reduction of Na2PdCl4 by ascorbic acid in the absence of a stabilizer at room temperature. The observations under transmission and scanning electron microscopy reveal that Pd nanoparticles with a size of 2–5 nm are uniformly dispersed on the surface of the Co(OH)2 nanoplates. In catalytic test, the conversion of 4-nitrophenol to 4-aminophenol is completed within 6 min in the presence of Co(OH)2-Pd(1000) nanoplates with 2.18 at.% Pd, and the corresponding kinetic constant is 0.0089 s-1 in the first test. The catalyst retains relatively high activity after several cycles. The results demonstrate that the Co(OH)2-Pd(1000) nanoplates exhibit high catalytic activity toward the reduction of 4-nitrophenol in the presence of NaBH4.
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