Metal‐ organic frameworks and their derivatives as anode material in lithium‐ion batteries: Recent advances towards novel configurations

International Journal of Energy ResearchEarly View REVIEW PAPER Metal-organic frameworks and their derivatives as anode material in lithium-ion batteries: Recent advances towards novel configurations Rajnish Kaur, Rajnish Kaur Department of Physics, Panjab University (PU), Chandigarh, IndiaSearch for more papers by this authorVarun A. Chhabra, Varun A. Chhabra Chitkara University Institute of Engineering and Technology, Chitkara University, Punjab, India Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of KoreaSearch for more papers by this authorVikas Chaudhary, Vikas Chaudhary Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, IndiaSearch for more papers by this authorKumar Vikrant, Kumar Vikrant Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of KoreaSearch for more papers by this authorSurya Kant Tripathi, Surya Kant Tripathi Department of Physics, Panjab University (PU), Chandigarh, IndiaSearch for more papers by this authorYanjie Su, Yanjie Su Department of Micro/Nano Electronics, Key Laboratory for Thin Film and Microfabrication (Ministry of Education), Shanghai Jiao Tong University, Shanghai, P.R. ChinaSearch for more papers by this authorParveen Kumar, Parveen Kumar Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, IndiaSearch for more papers by this authorKi-Hyun Kim, Corresponding Author Ki-Hyun Kim kkim61@hanyang.ac.kr orcid.org/0000-0003-0487-4242 Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of Korea Correspondence Ki-Hyun Kim, Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Republic of Korea. Email: kkim61@hanyang.ac.kr Akash Deep, Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India. Email: dr.akashdeep@gmail.comSearch for more papers by this authorAkash Deep, Corresponding Author Akash Deep dr.akashdeep@gmail.com Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India Correspondence Ki-Hyun Kim, Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Republic of Korea. Email: kkim61@hanyang.ac.kr Akash Deep, Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India. Email: dr.akashdeep@gmail.comSearch for more papers by this author Rajnish Kaur, Rajnish Kaur Department of Physics, Panjab University (PU), Chandigarh, IndiaSearch for more papers by this authorVarun A. Chhabra, Varun A. Chhabra Chitkara University Institute of Engineering and Technology, Chitkara University, Punjab, India Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of KoreaSearch for more papers by this authorVikas Chaudhary, Vikas Chaudhary Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, IndiaSearch for more papers by this authorKumar Vikrant, Kumar Vikrant Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of KoreaSearch for more papers by this authorSurya Kant Tripathi, Surya Kant Tripathi Department of Physics, Panjab University (PU), Chandigarh, IndiaSearch for more papers by this authorYanjie Su, Yanjie Su Department of Micro/Nano Electronics, Key Laboratory for Thin Film and Microfabrication (Ministry of Education), Shanghai Jiao Tong University, Shanghai, P.R. ChinaSearch for more papers by this authorParveen Kumar, Parveen Kumar Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, IndiaSearch for more papers by this authorKi-Hyun Kim, Corresponding Author Ki-Hyun Kim kkim61@hanyang.ac.kr orcid.org/0000-0003-0487-4242 Department of Civil and Environmental Engineering, Hanyang University, Seoul, Republic of Korea Correspondence Ki-Hyun Kim, Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Republic of Korea. Email: kkim61@hanyang.ac.kr Akash Deep, Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India. Email: dr.akashdeep@gmail.comSearch for more papers by this authorAkash Deep, Corresponding Author Akash Deep dr.akashdeep@gmail.com Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Chandigarh, India Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India Correspondence Ki-Hyun Kim, Department of Civil and Environmental Engineering, Hanyang University, 222 Wangsimni-Ro, Seoul 04763, Republic of Korea. Email: kkim61@hanyang.ac.kr Akash Deep, Material Science and Sensor Applications (MSSA), Central Scientific Instruments Organization (CSIR-CSIO), Sector 30 C, Chandigarh 160030, India. Email: dr.akashdeep@gmail.comSearch for more papers by this author First published: 23 May 2022 https://doi.org/10.1002/er.8046 Rajnish Kaur, Varun A. Chhabra, Vikas Chaudhary are first authors and contributed equally to this work. Funding information: National Research Foundation of Korea (NRF) funded by the Ministry of Science and ITC (MSIT) of Korean government, Grant/Award Number: 2021R1A3B1068304; UGC, India, Grant/Award Number: PH/20-21/0192 Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Summary Lithium-ion batteries (LIBs) have drawn extensive research interests due to their noticeably enhanced gravimetric energy density relative to other chemical batteries. The potential utility of metal-organic frameworks (MOFs) and their derivatives has recently been recognized as highly effective anode components for LIBs because they can be tuned to select specific metal sites and/or to adjust pore sizes. In this work, their electrochemical performance as anodic materials is carefully evaluated with respect to lithium-ions storage capacity, energy/power, stability, and flexibility. Furthermore, through the coordination of the organic linker and metal center, MOFs can benefit from enhanced catalytic activities in the design of advanced LIBs. For future research for next-generation LIBs, scientific focus should be placed on the development of diverse features of MOF-based composites such as core-shell MOFs, mono/bi-metal doped MOFs, dual organic linker-based MOFs, MOFs@MOFs core shell structure, and dual organic ligands-based MOF. As such, MOF-based LIB electrode materials are expected to expand their utility with the improvement in topology and functionality in association with the dimensionality, pore size, and surface area. Open Research DATA AVAILABILITY STATEMENT The data that supports the findings of this study are available in the supplementary material of this article. Supporting Information Filename Description er8046-sup-0001-Supinfo.docxWord 2007 document , 290 KB Appendix S1. Supporting Information. Figure S1. A schematic of the synthesis procedure use to prepare the Co3O4/nitrogen doped porous carbon composite from ZIF-67 [1]. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Early ViewOnline Version of Record before inclusion in an issue RelatedInformation