MECHNICAL STRENGTH AND DURABILITY OF ALKALI-ACTIVATED FLY ASH/SLAG CONCRETE

磨细高炉矿渣 材料科学 抗压强度 粉煤灰 硅酸盐水泥 极限抗拉强度 水泥 硅酸钠 水合硅酸钙 熔渣(焊接) 耐久性 复合材料 硅酸铝 杨氏模量 化学 催化作用 生物化学
作者
Maochieh Chi
出处
期刊:Journal of Marine Science and Technology 卷期号:24 (5): 958-967 被引量:8
标识
DOI:10.6119/jmst-016-0603-1
摘要

This study investigated the mechanical strength and durability of alkali-activated binders composed of blends of fly ash (FA) and ground granulated blast furnace slag. Five samples with FA/slag ratios of 100/0, 75/25, 50/50, 25/75, and 0/100 by mass were employed to prepare alkali-activated FA/slag (AAFS) concrete. Sodium oxide (Na_2O) concentrations of 6% and 8% of binder weight and activator modulus ratios (mass ratio of SiO_2 to Na_2O) of 0.8, 1.0, and 1.23 were used to prepare alkaline activators. Test results revealed that higher slag contents, Na_2O concentrations, and activator modulus ratios increased the compressive strength and splitting tensile strength of AAFS concrete. The total charge passed through AAFS concrete was between 2500 and 4000 C, higher than that passed through reference ordinary Portland cement (OPC) concrete. However, AAFS concrete demonstrated higher performance than that of OPC concrete when exposed to sulfate. According to scanning electron microscopy observations, the main hydration products of AAFS concrete were amorphous alkaline aluminosilicate and low-crystalline calcium silicate hydrate gel. As the slag content increased, the amount of C-S-H gel increased and that of A-S-H gel decreased. According to the results, 100% slag-based AAFS concrete with a Na_2O concentration of 8% and activator modulus ratio of 1.23 offers superior performance.
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