光催化
罗丹明B
材料科学
表面光电压
光谱学
高分辨率透射电子显微镜
扫描电子显微镜
漫反射红外傅里叶变换
载流子
可见光谱
带隙
电子顺磁共振
分析化学(期刊)
光化学
透射电子显微镜
化学工程
纳米技术
化学
复合材料
光电子学
核磁共振
有机化学
物理
催化作用
工程类
量子力学
作者
Mei Yang,Qi Yang,Junbo Zhong,Shengtian Huang,Jianzhang Li,Jiabo Song,Clemens Burda
标识
DOI:10.1016/j.apsusc.2017.04.206
摘要
Previous studies have well established that the photocatalytic performance of BiOF is greatly inhibited by its inherent drawbacks, which are the wide band gap and high recombination of photo-generated charge carriers. Therefore, it is necessary to promote the photocatalytic activity of BiOF. In this work, a series of novel Ag2O/BiOF composites were prepared by a facile precipitation method and characterized by X-ray diffractometry (XRD), UV–vis diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), high-resolution transmission electron microscopy (HRTEM), surface photovoltage (SPV) spectroscopy, and electron spin-resonance (ESR) spectroscopy. The photocatalytic characteristics of Rhodamine B (RhB) discoloration under simulated sunlight and visible-light irradiation were studied. The results revealed that the sample with 1.0% molar ratio of Ag/Bi displayed the best photocatalytic performance towards RhB discoloration and all the studied composites in this work displayed a higher photocatalytic activity than the bare BiOF. Based on the results of “band edge potential” of Ag2O and BiOF, SPV and ESR, charge separation and transportation mechanisms are suggested. Under simulated sunlight illumination, the charge separation and transport mechanism of the photo-induced charge pairs followed a Z-scheme.
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