Pore-Scale Visualized Transport and Retention of Fibrous and Fragmental Microplastics in Porous Media under Various Surfactant Conditions

For advancing current knowledge on the transport of microplastics (MPs) in the environment, this study used a real-time pore-scale visualization and quantitative system to examine the motions and mobility of fibrous and fragmental MPs under various surfactant (AEO, CTAC, and AES) and electrolyte conditions. The videos showed that fibrous MPs formed tangles through entanglement, which moved in an axial direction aligned with the flow streamline. Both fibrous and fragmental MPs showed suspended movement as well as surface movement (e.g., sliding, rolling, and saltating) in the porous media. Some deposited fibrous MPs showed flexible deformation due to shear flow. Compared to fragmental MPs, fibrous MPs showed lower mobility due to the tendency to deposit and clog the porous media. The mobility of fragmental MPs was enhanced in the presence of AEO but remained relatively unchanged with AES. In the presence of CTAC, the mobility of fragmental MPs was slightly inhibited under low ionic strength (IS) conditions but remarkably enhanced under high IS conditions. However, the mobility of fibrous MPs was largely unaffected by the surfactants. Both the numerical model and FDLVO calculations effectively described the transport and deposition of MPs in porous media.