Embedding Plate‐Like Pyrochlore in Perovskite Phase to Enhance Energy Storage Performance of BNT‐Based Ceramic Capacitors

Abstract Next‐generation electrical and electronic systems rely on the development of efficient energy‐storage dielectric ceramic capacitors. However, achieving a synergistic enhancement in the polarization and in the breakdown field strength ( E b ) presents a considerable challenge. Herein, a heterogeneous combination strategy involving embedding a high E b plate‐like pyrochlore phase in a high‐polarization perovskite phase is proposed. The embedded plate‐like pyrochlore increases the breakdown field strength and promotes the dynamic polarization response. Meanwhile, the strong spin–orbit coupling effect of the 5d electrons is conducive to the maintenance of the high polarization value of the perovskite. Consequently, the prepared multilayer ceramic capacitor (MLCC) exhibits an ultrahigh E b and a high polarization. More specifically, an energy storage density ( W rec ) of 14.9 J cm −3 with an efficiency of up to 93.4% is achieved for the optimized pyrochlore/perovskite phase. Furthermore, the MLCCs also exhibits an W rec of ≈ 7.7 J cm −3 ± 4.5% in the temperature range of −50–180 °C. Therefore, this heterogeneous combination strategy therefore provides a simple and effective method for improving the energy‐storage performances of dielectric ceramic capacitors.