Cesium adsorption from an aqueous medium for environmental remediation: A comprehensive analysis of adsorbents, sources, factors, models, challenges, and opportunities

Considering the widespread and indispensable nature of nuclear energy for future power generation, there is a concurrent increase in the discharge of radioactive Cs into water streams. Recent studies have demonstrated that adsorption is crucial in removing Cs from wastewater for environmental remediation. However, the existing literature lacks comprehensive studies on various adsorption methods, the capacities or efficiencies of adsorbents, influencing factors, isotherm and kinetic models of the Cs adsorption process. A bibliometric and comprehensive analysis was conducted using 1179 publications from the Web of Science Core Collection spanning from 2014 to 2023. It reviews and summarizes current publication trends, active countries, adsorption methods, adsorption capacities or efficiencies of adsorbents, tested water sources, influencing factors, isotherm, and kinetic models of Cs adsorption. The selection of suitable adsorbents and operating parameters is identified as a crucial factor. Over the past decade, due to their notable capacity for Cs adsorption, considerable research has focused on novel adsorbents, such as Prussian blue, graphene oxide, hydrogel, and nanoadsorbents (NA). However, there remains a need for further development of application-oriented laboratory-scale experiments. Future research directions should encompass exploring adsorption mechanisms, developing new adsorbents or their combinations, practical applications of lab-scale studies, and recycling radioactive Cs from wastewater. Drawing upon this literature review, we present the most recent research patterns concerning adsorbents to remove Cs, outline potential avenues for future research, and delineate the obstacles hindering effective adsorption. This comprehensive bibliometric review provides valuable insights into prevalent research focal points and emerging trends, serving as a helpful resource for researchers and policymakers seeking to understand the dynamics of adsorbents for Cs removal from water.