已入深夜,您辛苦了!由于当前在线用户较少,发布求助请尽量完整的填写文献信息,科研通机器人24小时在线,伴您度过漫漫科研夜!祝你早点完成任务,早点休息,好梦!

Continuous solvothermal synthesis of copper nanoparticles in supercritical ethanol

超临界流体 物理 纳米颗粒 乙醇 化学工程 纳米技术 热力学 有机化学 化学 材料科学 量子力学 工程类
作者
Panpan Sun,Chuanjiang Sun,Zhaobin Lv,Shuzhong Wang
出处
期刊:Physics of Fluids [American Institute of Physics]
卷期号:36 (10)
标识
DOI:10.1063/5.0221244
摘要

Continuous supercritical solvothermal synthesis of copper nanoparticles is of great interest due to its enormous potential in energy sustainability. In this study, supercritical methanol and ethanol were used as reaction solvents, copper nitrate [Cu(NO3)2] and copper acetate [Cu(CH3COO)2] were used as representative inorganic and organic copper precursors. Finally, macromolecular organic polymers [polyvinylpyrrolidone, PVP, (C6H9NO)n] and long-chain fatty acids [decanoic acid, CH3(CH2)8COOH] were used as ligands to study cooper nanocrystals' formation mechanism. The results showed that a higher conversion rate of Cu2+ and smaller crystals were obtained when supercritical ethanol acted as solvent due to the variation of hydrogen bonding degree. Compared with NO3−, more thorough conversion and faster nucleation can be realized when CH3COO− acts as precursor anion. These arise from the diverse chemical bonding degree and functional group. Moreover, with the addition of macromolecular PVP, the dispersibility of obtained copper nanoparticles was significantly better than with the reaction of decanoic acid addition. Moreover, with increase in the PVP concentration, the morphology of the product became more and more regular, the distribution became more and more even, which was caused by inconsistent growth rates of each crystal surface under different PVP concentrations. This research provides deep insight into the supercritical solvothermal black box and lays the foundation for industrial application of this technology.

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
2秒前
碇真嗣发布了新的文献求助10
3秒前
田田田完成签到,获得积分20
3秒前
5秒前
6秒前
轻爱完成签到,获得积分10
7秒前
赘婿应助苏同学采纳,获得10
9秒前
碇真嗣完成签到,获得积分20
9秒前
脑洞疼应助忆点儿孤狼采纳,获得10
9秒前
陈海明发布了新的文献求助30
10秒前
10秒前
HDD发布了新的文献求助10
14秒前
16秒前
扶摇直上发布了新的文献求助10
16秒前
ppg123应助胡通才是ke研通采纳,获得10
18秒前
archer01发布了新的文献求助10
18秒前
陈海明完成签到,获得积分20
19秒前
AURORA完成签到,获得积分10
20秒前
mm关注了科研通微信公众号
20秒前
wangting发布了新的文献求助10
22秒前
24秒前
扶摇直上完成签到,获得积分20
25秒前
HDD完成签到,获得积分10
25秒前
Jasper应助xinmindeng采纳,获得10
26秒前
kll9797发布了新的文献求助30
27秒前
wushuping完成签到,获得积分10
28秒前
斯文败类应助科研通管家采纳,获得10
29秒前
科研通AI2S应助科研通管家采纳,获得80
29秒前
不配.应助科研通管家采纳,获得10
29秒前
29秒前
科研通AI2S应助科研通管家采纳,获得10
29秒前
双黄应助uziMOF采纳,获得10
29秒前
29秒前
科研通AI2S应助科研通管家采纳,获得10
29秒前
田様应助科研通管家采纳,获得10
29秒前
29秒前
Hello应助科研通管家采纳,获得10
29秒前
lehha发布了新的文献求助10
30秒前
30秒前
WL发布了新的文献求助10
34秒前
高分求助中
The late Devonian Standard Conodont Zonation 2000
Nickel superalloy market size, share, growth, trends, and forecast 2023-2030 2000
The Lali Section: An Excellent Reference Section for Upper - Devonian in South China 1500
Smart but Scattered: The Revolutionary Executive Skills Approach to Helping Kids Reach Their Potential (第二版) 1000
Very-high-order BVD Schemes Using β-variable THINC Method 830
Mantiden: Faszinierende Lauerjäger Faszinierende Lauerjäger 800
PraxisRatgeber: Mantiden: Faszinierende Lauerjäger 800
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3248529
求助须知:如何正确求助?哪些是违规求助? 2891960
关于积分的说明 8269265
捐赠科研通 2559983
什么是DOI,文献DOI怎么找? 1388824
科研通“疑难数据库(出版商)”最低求助积分说明 650913
邀请新用户注册赠送积分活动 627798