Azobenzene‐Functionalized Semicrystalline Liquid Crystal Elastomer Springs for Underwater Soft Robotic Actuators

Abstract As actuated devices become smaller and more complex, there is a need for smart materials and structures that directly function as complete mechanical units without an external power supply. The strategy uses light‐powered, twisted, and coiled azobenzene‐functionalized semicrystalline liquid crystal elastomer (AC‐LCE) springs. This twisting and coiling, which has previously been used for only thermally, electrochemically, or absorption‐powered muscles, maximizes uniaxial and radial actuation. The specially designed photochemical muscles can undergo about 60% tensile stroke and provide 15 kJ m −3 of work capacity in response to light, thus providing about three times and two times higher performance, respectively, than previous azobenzene actuators. Since this actuation is photochemical, driven by ultraviolet (UV) light and reversed by visible light, isothermal actuation can occur in a range of environmental conditions, including underwater. In addition, photoisomerization of the AC‐LCEs enables unique latch‐like actuation, eliminating the need for continuous energy application to maintain the stroke. Also, as the light‐powered muscles processed to be either homochiral or heterochiral, the direction of actuation can be reversed. The presented approach highlights the novel capabilities of photochemical actuator materials that can be manipulated in untethered, isothermal, and wet environmental conditions, thus suggesting various potential applications, including underwater soft robotics.