化学
乙腈
N-溴代丁二酰亚胺
分析化学(期刊)
大气温度范围
热力学
色谱法
有机化学
物理
卤化
作者
Cheng Xie,Fuyi Sun,Xiujian Zhao,Wu Chen,Yuanyuan Che
标识
DOI:10.1021/acs.jced.3c00312
摘要
A transient hot-wire method was used in this work to measure the thermal conductivities of methyl 2-methyl-3-nitrobenzoate (MMN) + acetonitrile, N-bromosuccinimide (NBS) + acetonitrile, and MMN + NBS + acetonitrile in the temperature range of T = (300–340) K. For binary systems, measurements were made for the mass fractions of MMN (ω1) range from 0 to 0.45 and the mass fractions of NBS (ω2) range from 0 to 0.30. For the ternary system, measurements were carried out with the ω1 + ω2 range from 0 to 0.45. The expanded uncertainties of the experimental data were estimated to be 2%, while the confidence level was 0.95 (k = 2). The experimental data were correlated as a function of the mass fraction and temperature using a linear thermal conductivity model. The maximum absolute relative deviation between the experimental values and the calculated results from the fitting model were 0.60, 0.16, and 1.30%.
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