Geochemical modeling and hydrochemical analysis for water quality determination around mine drainage areas

Abstract Water sources in mining areas do not retain their natural quality due to the influence of mine drainage. Water quality test was through hydrochemical analysis, speciation modeling, and saturation indices. Water samples were analyzed for pH, conductivity, nitrate, phosphate, sulfate, chlorite, sodium, magnesium, calcium, turbidity, total hardness, lead, zinc, iron, copper, cadmium, manganese, nickel, and chromium. Mean values of turbidity (0.13 mg/L), lead (0.01 mg/L), and cadmium (6.40 mg/L) exceeded their permissible values for potable water. Multivariate statistical analysis shows geogenic and anthropogenic sources of chemical species. Chemical speciation shows that the cations exist mostly in their soluble and mobile forms as free ions. Water quality index of 35–45.5 shows good water for drinking, irrigation, and industrial uses. The values of 63.8–68.8 and 103–121 reflect suitable water for industrial and irrigation uses. The research is integrated and credible in predicting groundwater pollutants to solve water pollution problems. Practitioner Points The mean value of turbidity, Pb, and Cd exceeded the WHO/NSDWQ standards for potable water. Correlation and principal component analyses show that the chemical species are from both geogenic and anthropogenic sources. Chemical speciation shows that the cations exist in their soluble and mobile forms as free ions except Cr. Saturation indices show that the minerals anhydrite, anglesite, vivianite, langite, larnakite, melanterite, and mirabilite are undersaturated in the water sources. Water quality index shows that the water is more suitable for irrigation than drinking and industrial uses.