Photoreduction of Aqueous Protons Coupling with Alcohol Oxidation on a S‐Scheme Heterojunction Photocatalyst MnO/Carbon Nitride

Abstract Crystalline carbon nitride (CCN), derived from amorphous polymeric CN, is considered as a new generation of metal‐free photocatalyst because of its high crystallinity. In order to further promote the photocatalytic performance of CCN, p‐type MnO nanoparticles are in situ synthesized and merged with n‐type CCN through a one‐pot process to form p–n heterojunction. The formed interfacial electric field between the semiconductors with different work functions efficiently breaks the coulomb interaction between MnO and CCN. The prepared catalysts exhibit drastically increased photocatalytic hydrogen evolution (PHE) activity integrated with oxidation of alkyl and aryl alcohols under irradiation of visible light. In the aqueous solution of benzyl alcohol (BzOH), the hydrogen generation rate over MnO/CCN (39.58 µmol h −1 ) is nearly 7 times and 37 times that of pure CCN (5.76 µmol h −1 ) and CN (1.06 µmol h −1 ), respectively, combining with oxidation of BzOH to benzaldehyde. This work proposes an avenue for in situ construction of a novel 2D material‐based S‐scheme heterojunction and extends its application in solar energy conservation and utilization.